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Transactions of the INDIAN CERAMIC SOCIETY   Vol. 83  2024
Evaluation of Different Fly Ash-Blast Furnace Slag Formulations for Design of Geopolymers in Radioactivity Disposal Applications
Ritu Dharmendra Ambashta,1, 2, † Thomas C Alex,3, † Rashmi Singla,3, * Durga Prashanna Sahoo,3 Partha Sarathi Sarkar,1, 2 Rakesh Kumar Bajpai,1, 2 Yelemane Channabasappa Shivakumar,1 Smitha Manohar1 and Sanjay Kumar3
Pages : 178-187
DOI : 10.1080/0371750X.2024.2386521
Abstract
Geopolymers in radioactive waste management have in recent times gained dominance in disposal module acceptance. Here is a comparative study on formulations prepared from industrial wastes to be utilized as radionuclide disposal barriers in near surface disposal facilities (NSDFs). Different tools such as isocalorimetry, compressive strength, chemical durability were utilized for screening the formulations. Water leaching of the samples shows that the release of the ions to the leachant is minimal. Durability studies in acids (H2SO4, HCl and HNO3) show that the samples are mostly acid resistant. X-ray tomography suggests low pore volume change over a period of 2 years. The study concludes that the NSDF requirement of low permeability of water and better chemical durability criterion is met by the optimized geopolymerization formulation. [Keywords: Compressive strength, Geopolymer, Leaching, Nuclear waste immobilization, X-ray tomography]
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