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Transactions of the INDIAN CERAMIC SOCIETY   Vol. 54  1995
Redox Processing of Al20 3/Al Composite Materials
R. BHAT, D. D. UPADHYAYA, S. RAMANATHAN AND S. K. RoY
Pages : 234-236
DOI : 10.1080/0371750X.1995.10804731
Abstract
The co-continuous alumina/aluminium based composites show immense potential for high performance engineering applications where alumina offers superior stability to oxidation at elevated temperatures. In this paper preliminary results on fabrication of AI20/AI composites by a metathesis reaction between silicon dioxide preforms and molten aluminium are reported. The reaction ingredients employed were pure aluminium (commercial grade-IS) and optical grade silica glass. The transformation kinetics were studied in the temperature regimes of 900°-1300°C in 1 00°C steps and the various reaction times between 5.0 mins and 18.0 hrs. The composite growth took place through the formation of an intermediate phase and followed a linear rate behaviour. The width of the reaction interface decreased with the increase/decrease in temperature of the reaction. Typical growth rate~ of about 1.0 and 5.0 mm.h-1 were obtained at 1000° and 1200°C respectively. Bulk density of these composites was estimated to be 3.2 gm.cm-3 • Optical microscopy 1·evcalcd a continuous network of alumina phase interpenetrated by the tortuous microscopic channels of residual metallic phase.
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