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Transactions of the INDIAN CERAMIC SOCIETY   Vol. 65  2006
A Study on the Solubility Limit of Nd2O3 in ThO2-NdO1.5 Solid Solution
G. Panneerselvam, M. P. Antony and P.R Vasudeva Rao
Pages : 97-99
DOI :10.1080/0371750X.2006.11012282
Abstract
Thorium dioxide dissolves considerable amounts of rare earth oxides forming FCC fluorite-type solid solution. In the present study a series of solid solutions containing NdO1.5 in ThO2 were prepared by co-precipitation method. These solid solutions were characterized for their composition by standard wet-chemical analysis. Their bulk and theoretical densities were determined by immersion and X-ray techniques respectively. The extent of solubility of NdO1.5 in ThO2 matrix was determined using powder X-ray diffraction at 1473 K. The measured solubility of NdO1.5 was found to be in the range 45.7 to 46.2 mol%.
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